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Exergy and exergoeconomic analyses for integration of aromatics separation with aromatics upgrading

《化学科学与工程前沿(英文)》 2023年 第17卷 第2期   页码 183-193 doi: 10.1007/s11705-022-2192-9

摘要: Methanol to aromatics produces multiple products, resulting in a limited selectivity of xylene. Aromatics upgrading is an effective way to produce more valuable xylene product, and different feed ratios generate discrepant product distributions. This work integrates the aromatics separation with toluene disproportionation, transalkylation of toluene and trimethylbenzene, and isomerization of xylene and trimethylbenzene. Exergy and exergoeconomic analyses are conducted to give insights in the splitting ratios of benzene, toluene and heavy aromatics for aromatics upgrading. First, a detailed simulation model is developed in Aspen HYSYS. Then, 300 splitting ratio sets of benzene and toluene for conversion are studied to investigate the process performances. The results indicate that there are different preferences for the splitting ratios of benzene and toluene in terms of exergy and exergoeconomic performances. The process generates lower total exergy destruction when the splitting ratio of toluene varies between 0.07 and 0.18, and that of benzene fluctuates between 0.55 and 0.6. Nevertheless, the process presents lower total product unit cost with the splitting ratio of toluene less than 0.18 and that of benzene fluctuating between 0.44 and 0.89. Besides, it is found that distillation is the biggest contributor to the total exergy destruction, accounting for 94.97%.

关键词: aromatics separation and upgrading     variant splitting ratios     total exergy destruction     total product unit cost    

Performance analysis of combined cycle power plant

Nikhil DEV,Rajesh ATTRI

《能源前沿(英文)》 2015年 第9卷 第4期   页码 371-386 doi: 10.1007/s11708-015-0371-9

摘要: Combined cycle power plants (CCPPs) are in operation with diverse thermodynamic cycle configurations. Assortment of thermodynamic cycle for scrupulous locality is dependent on the type of fuel available and different utilities obtained from the plant. In the present paper, seven of the practically applicable configurations of CCPP are taken into consideration. Exergetic and energetic analysis of each component of the seven configurations is conducted with the help of computer programming tool, i.e., engineering equation solver (EES) at different pressure ratios. For Case 7, the effects of pressure ratio, turbine inlet temperature and ambient relative humidity on the first and second law is studied. The thermodynamics analysis indicates that the exergy destruction in various components of the combined cycle is significantly affected by the overall pressure ratio, turbine inlet temperature and pressure loss in air filter and less affected by the ambient relative humidity.

关键词: first-law     second-law     exergy destruction     components    

Exergy analysis of R1234ze(Z) as high temperature heat pump working fluid with multi-stage compression

Bin HU, Di WU, L.W. WANG, R.Z. WANG

《能源前沿(英文)》 2017年 第11卷 第4期   页码 493-502 doi: 10.1007/s11708-017-0510-6

摘要: In this paper, the simulation approach and exergy analysis of multi-stage compression high temperature heat pump (HTHP) systems with R1234ze(Z) working fluid are conducted. Both the single-stage and multi-stage compression cycles are analyzed to compare the system performance with 120°C pressurized hot water supply based upon waste heat recovery. The exergy destruction ratios of each component for different stage compression systems are compared. The results show that the exergy loss ratios of the compressor are bigger than that of the evaporator and the condenser for the single-stage compression system. The multi-stage compression system has better energy and exergy efficiencies with the increase of compression stage number. Compared with the single-stage compression system, the coefficient of performance (COP) improvements of the two-stage and three-stage compression system are 9.1% and 14.6%, respectively. When the waste heat source temperature is 60°C, the exergy efficiencies increase about 6.9% and 11.8% for the two-stage and three-stage compression system respectively.

关键词: multi-stage compression     high temperature heat pump     heat recovery     exergy destruction     R1234ze(Z) working fluid    

Energy and exergy analysis of syngas production from different biomasses through air-steam gasification

S. Rupesh,C. Muraleedharan,P. Arun

《能源前沿(英文)》 2020年 第14卷 第3期   页码 607-619 doi: 10.1007/s11708-016-0439-1

摘要: Gasification is a thermo-chemical reaction which converts biomass into fuel gases in a reactor. The efficiency of conversion depends on the effective working of the gasifier. The first step in the conversion process is the selection of a suitable feedstock capable of generating more gaseous fuels. This paper analyses the performance of different biomasses during gasification through energy and exergy analysis. A quasi-equilibrium model is developed to simulate and compare the feasibility of different biomass materials as gasifier feedstock. Parametric studies are conducted to analyze the effect of temperature, steam to biomass ratio and equivalence ratio on energy and exergy efficiencies. Of the biomasses considered, sawdust has the highest energy and exergy efficiencies and lowest irreversibility. At a gasification temperature of 1000 K, the steam to biomass ratio of unity and the equivalence ratio of 0.25, the energy efficiency, exergy efficiency and irreversibility of sawdust are 35.62%, 36.98% and 10.62 MJ/kg, respectively. It is also inferred that the biomass with lower ash content and higher carbon content contributes to maximum energy and exergy efficiencies.

关键词: gasification     modeling     energy     exergy     syngas    

Exergy analysis of multi-stage crude distillation units

Xingang LI, Canwei LIN, Lei WANG, Hong LI

《化学科学与工程前沿(英文)》 2013年 第7卷 第4期   页码 437-446 doi: 10.1007/s11705-013-1349-y

摘要: This paper aims to investigate the multi-stage effect on crude distillation units (CDUs) in thermodynamics. In this regard, we proposed three-, four-, five-, and six-stage CDU processes with all variables constrained to be almost the same except for the number of stages. We also analyzed the energy and exergy to assess the energy consumed by each process. Because additional distillation units would share the processing load and thus prevent products with low boiling points from overheating, the heat demand of the CDUs decreases with increasing stages and thus reduces the heat supply. Exergy loss is considered as a key parameter to assess these processes. When the exergy losses in heat exchangers are disregarded, the three- and four-stage CDUs have lower exergy losses than the five- and six-stage CDUs. When the overall exergy losses are considered, the optimum number of stages of CDUs depends on the exergy efficiency of heat integration.

关键词: exergy     exergy loss     crude oil distillation     multi-stage     energy saving    

A review on membrane distillation in process engineering: design and exergy equations, materials and

《化学科学与工程前沿(英文)》 2022年 第16卷 第5期   页码 592-613 doi: 10.1007/s11705-021-2105-3

摘要: One of the problems that most afflicts humanity is the lack of clean water. Water stress, which is the pressure on the quantity and quality of water resources, exists in many places throughout the World. Desalination represents a valid solution to the scarcity of fresh water and several technologies are already well applied and successful (such as reverse osmosis), producing about 100 million m3·d−1 of fresh water. Further advances in the field of desalination can be provided by innovative processes such as membrane distillation. The latter is of particular interest for the treatment of waste currents from conventional desalination processes (for example the retentate of reverse osmosis) as it allows to desalt highly concentrated currents as it is not limited by concentration polarization phenomena. New perspectives have enhanced research activities and allowed a deeper understanding of mass and heat transport phenomena, membrane wetting, polarization phenomena and have encouraged the use of materials particularly suitable for membrane distillation applications. This work summarizes recent developments in the field of membrane distillation, studies for module length optimization, commercial membrane modules developed, recent patents and advancement of membrane material.

关键词: membrane distillation     recent developments     heat and mass transfer     wetting     membrane material    

Exergy analysis and performance enhancement of isopropanol-acetone-hydrogen chemical heat pump

Min XU, Jun CAI, Xiulan HUAI

《能源前沿(英文)》 2017年 第11卷 第4期   页码 510-515 doi: 10.1007/s11708-017-0508-0

摘要: Exergy loss analysis was conducted to identify the irreversibility in each component of the isopropanol-acetone-hydrogen chemical heat pump (IAH-CHP). The results indicate that the highest irreversibility on a system basis occurs in the distillation column. Moreover, the effect of operating parameters on thermodynamic performances of the IAH-CHP was studied and the optimal conditions were obtained. Finally, the potential methods to reduce the irreversibility of the IAH-CHP system were investigated. It is found that reactive distillation is apromising alternative. The enthalpy and exergy efficiency of the IAH-CHP with reactive distillation increases by 24.1% and 23.2%, respectively.

关键词: waste heat reuse     chemical heat pump     exergy analysis     isopropanol    

Entropy flow, entropy generation, exergy flux, and optimal absorbing temperature in radiative transfer

Zeshao CHEN, Songping MO, Peng HU, Shouli JIANG, Gang WANG, Xiaofang CHENG,

《能源前沿(英文)》 2010年 第4卷 第3期   页码 301-305 doi: 10.1007/s11708-010-0006-0

摘要: Taking nonequilibrium radiative heat transfer between two surfaces as an example, the nonequilibrium thermodynamics of radiation is studied and discussed. The formulas of entropy flow, entropy generation, exergy flux, and optimal temperature of absorbing surface for maximum exergy output are derived. The result is a contribution to the thermodynamic analysis and optimization of solar energy utilization and can be applied in more complex radiative heat transfer cases.

关键词: radiative heat transfer     entropy generation     exergy     thermodynamics    

Simultaneous removal of total oxidizable carbon, phosphate and various metallic ions from HO solution

《化学科学与工程前沿(英文)》 2023年 第17卷 第4期   页码 470-482 doi: 10.1007/s11705-022-2231-6

摘要: Amino-functionalized zirconia was synthesized by the co-condensation method using zirconium butanol and 3-aminopropyltriethoxy silane for the simultaneous removal of various impurities from aqueous 30% H2O2 solution. The results of Fourier transform infrared (FTIR) and Zeta potential showed that the content of N in amino-functionalized zirconia increased with the added amount of 3-aminopropyltriethoxy silane. Accordingly, the removal efficiency of total oxidizable carbon, phosphate and metallic ions from the H2O2 solution increased. The adsorbent with an N content of 1.62% exhibited superior adsorption performance. The removal efficiency of 82.7% for total oxidizable carbon, 34.2% for phosphate, 87.1% for Fe3+, 83.2% for Al3+, 55.1% for Ca2+ and 66.6% for Mg2+, with a total adsorption capacity of 119.6 mg·g–1, could be achieved. The studies conducted using simulated solutions showed that the adsorption process of phosphate on amino-functionalized zirconia is endothermic and spontaneous, and the behaviors could be well described by the pseudo-second-order model and Langmuir model with a maximum adsorption capacity of 186.7 mg·g–1. The characterizations of the spent adsorbents by Zeta potential, FTIR and X-ray photoelectron spectroscopy revealed that the adsorption mechanism of phosphate is predominantly electrostatic attraction by the protonated functional groups and complementary ligand exchange with zirconium hydroxyl groups.

关键词: adsorption     zirconia     total oxidizable carbon     phosphate     metallic ions     hydrogen peroxide    

Implementation of total Lagrangian formulation for the elasto-plastic analysis of plane steel frames

Bing XIA, Yuching WU, Zhanfei HUANG

《结构与土木工程前沿(英文)》 2012年 第6卷 第3期   页码 257-266 doi: 10.1007/s11709-012-0163-9

摘要: In this paper, the co-rotational total Lagrangian forms of finite element formulations are derived to perform elasto-plastic analysis for plane steel frames that either experience increasing external loading at ambient temperature or constant external loading at elevated temperatures. Geometric nonlinearities and thermal-expansion effects are considered. A series of programs were developed based on these formulations. To verify the accuracy and efficiency of the nonlinear finite element programs, numerical benchmark tests were performed, and the results from these tests are in a good agreement with the literature. The effects of the nonlinear terms of the stiffness matrices on the computational results were investigated in detail. It was also demonstrated that the influence of geometric nonlinearities on the incremental steps of the finite element analysis for plane steel frames in the presence of fire is limited.

关键词: co-rotational     total Lagrangian     geometrical nonlinearity     fire     elasto-plastic    

Critical flow-storm approach to total maximum daily load (TMDL) development: an analytical conceptual

Zhang Harry, Yu Shaw

《环境科学与工程前沿(英文)》 2008年 第2卷 第3期   页码 267-273 doi: 10.1007/s11783-008-0058-0

摘要: One of the key challenges in the total maximum daily load (TMDL) development process is how to define the critical condition for a receiving waterbody. The main concern in using a continuous simulation approach is the absence of any guarantee that the most critical condition will be captured during the selected representative hydrologic period, given the scarcity of long-term continuous data. The objectives of this paper are to clearly address the critical condition in the TMDL development process and to compare continuous and event-based approaches in defining critical condition during TMDL development for a waterbody impacted by both point and nonpoint source pollution. A practical, event-based critical flow-storm (CFS) approach was developed to explicitly addresses the critical condition as a combination of a low stream flow and a storm event of a selected magnitude, both having certain frequencies of occurrence. This paper illustrated the CFS concept and provided its theoretical basis using a derived analytical conceptual model. The CFS approach clearly defined a critical condition, obtained reasonable results and could be considered as an alternative method in TMDL development.

关键词: representative hydrologic     occurrence     simulation approach     scarcity     alternative    

Search for a natural scientific measure of economy

John E COULTER

《环境科学与工程前沿(英文)》 2011年 第5卷 第1期   页码 111-118 doi: 10.1007/s11783-011-0285-7

摘要: Through human history, wealth has been measured in grain, gold, and, now, dollars. Though counterfeiting of coins and notes goes back a long way, it is only with electronic financial accounting in a global economy tainted by toxic loans and imaginary funds that there is an urgency to search for a realistic objective way to monitor and regulate what we are doing to our Earth and ourselves. Various schemes using analysis of utility functions, oil equivalents, entropy, energy, and other units have been tried and, while helping to understand some basic processes and flows, have always been swamped by the machinations of financiers and the attention big sums of money attract. Now, the concept of exergy, pioneered in Eastern Europe in the 1950s, is being researched, developed, and applied, especially in China, driven by the desperation to measure the reality beyond the twin specters of global financial and environmental crises. A rough inventory of the matter in the biosphere at the coordinate details of an angstrom and an appreciation of how humans harness and manipulate electromagnetic forces can be enlightening as to what is and is not sustainable. Without that understanding, any financial estimate and proposed stimulus packages or IMF reform will be wildly wrong and may even be headed in the wrong direction.

关键词: climate change     financial crisis     energy     exergy     environment    

From total quality management to Quality 4.0: A systematic literature review and future research agenda

《工程管理前沿(英文)》 2023年 第10卷 第2期   页码 191-205 doi: 10.1007/s42524-022-0243-z

摘要: Quality 4.0 is an emerging concept that has been increasingly appreciated because of the intensification of competition, continually changing customer requirements and technological evolution. It deals with aligning quality management practices with the emergent capabilities of Industry 4.0 to improve cost, time, and efficiency and increase product quality. This article aims to comprehensively review extant studies related to Quality 4.0 to uncover current research trends, distil key research topics, and identify areas for future research. Thus, 46 journal articles extracted from the Scopus database from 2017 to 2022 were collected and reviewed. A descriptive analysis was first performed according to the year-wise publication, sources of publication, and research methods. Then, the selected articles were analyzed and classified according to four research themes: Quality 4.0 concept, Quality 4.0 implementation, quality management in Quality 4.0, and Quality 4.0 model and application. By extracting the literature review findings, we identify the Quality 4.0 definitions and features, develop the quality curve theory, and highlight future research opportunities. This study supports practitioners, managers, and academicians in effectively recognizing and applying Quality 4.0 to enhance customer satisfaction, achieve innovation enterprise efficiency, and increase organizational competitiveness in the era of Industry 4.0.

关键词: quality management     Quality 4.0     Industry 4.0     literature review     predictive quality    

Total stress rapid drawdown analysis of the Pilarcitos Dam failure using the finite element method

Daniel R. VANDENBERGE

《结构与土木工程前沿(英文)》 2014年 第8卷 第2期   页码 115-123 doi: 10.1007/s11709-014-0249-7

摘要: Rapid drawdown is a critical design condition for the upstream or riverside slope of earth dams and levees. A new total stress rapid drawdown method based on finite element analysis is used to analyze the rapid drawdown failure that occurred at Pilarcitos Dam in 1969. Effective consolidation stresses in the slope prior to drawdown are determined using linear elastic finite element analysis. Undrained strengths from isotropically consolidated undrained (ICU) triaxial compression tests are related directly to the calculated consolidation stresses and assigned to the elements in the model by interpolation. Two different interpretations of the undrained strength envelope are examined. Strength reduction finite element analyses are used to evaluate stability of the dam. Back analysis suggests that undrained strengths from ICU tests must be reduced by 30% for use with this rapid drawdown method. The failure mechanism predicted for Pilarcitos Dam is sensitive to the relationship between undrained strength and consolidation stress.

关键词: rapid drawdown     finite element     total stress     slope stability    

A total torque index for dynamic performance evaluation of a radial symmetric six-legged robot

Kejia LI, Xilun DING, Marco CECCARELL

《机械工程前沿(英文)》 2012年 第7卷 第2期   页码 219-230 doi: 10.1007/s11465-012-0320-9

摘要:

This article focuses on the dynamic index and performance of a radial symmetric six-legged robot. At first the structure of the robot is described in brief and its inverse kinematics is presented. Then the dynamic model is formulated as based on the Lagrange equations. A novel index of total torque is proposed by considering the posture of the supporting legs. The new index can be used to optimize the leg’s structure and operation for consuming minimum power and avoiding unstable postures of the robot. A characterization of the proposed six-legged robot is obtained by a parametric analysis of robot performance through simulation using the presented dynamic model. Main influences are outlined as well as the usefulness of the proposed performance index.

关键词: six-legged robots     dynamic modeling     performance index    

标题 作者 时间 类型 操作

Exergy and exergoeconomic analyses for integration of aromatics separation with aromatics upgrading

期刊论文

Performance analysis of combined cycle power plant

Nikhil DEV,Rajesh ATTRI

期刊论文

Exergy analysis of R1234ze(Z) as high temperature heat pump working fluid with multi-stage compression

Bin HU, Di WU, L.W. WANG, R.Z. WANG

期刊论文

Energy and exergy analysis of syngas production from different biomasses through air-steam gasification

S. Rupesh,C. Muraleedharan,P. Arun

期刊论文

Exergy analysis of multi-stage crude distillation units

Xingang LI, Canwei LIN, Lei WANG, Hong LI

期刊论文

A review on membrane distillation in process engineering: design and exergy equations, materials and

期刊论文

Exergy analysis and performance enhancement of isopropanol-acetone-hydrogen chemical heat pump

Min XU, Jun CAI, Xiulan HUAI

期刊论文

Entropy flow, entropy generation, exergy flux, and optimal absorbing temperature in radiative transfer

Zeshao CHEN, Songping MO, Peng HU, Shouli JIANG, Gang WANG, Xiaofang CHENG,

期刊论文

Simultaneous removal of total oxidizable carbon, phosphate and various metallic ions from HO solution

期刊论文

Implementation of total Lagrangian formulation for the elasto-plastic analysis of plane steel frames

Bing XIA, Yuching WU, Zhanfei HUANG

期刊论文

Critical flow-storm approach to total maximum daily load (TMDL) development: an analytical conceptual

Zhang Harry, Yu Shaw

期刊论文

Search for a natural scientific measure of economy

John E COULTER

期刊论文

From total quality management to Quality 4.0: A systematic literature review and future research agenda

期刊论文

Total stress rapid drawdown analysis of the Pilarcitos Dam failure using the finite element method

Daniel R. VANDENBERGE

期刊论文

A total torque index for dynamic performance evaluation of a radial symmetric six-legged robot

Kejia LI, Xilun DING, Marco CECCARELL

期刊论文